The number of hydrogen atom(s) attached to phosphorus atom in hypophosphorous
acid is :
Chemistrychemistry-in-everyday-life2005easy
Which one of the following types of drugs reduces fever?
Chemistrys-block-elements2005medium
Based on lattice energy and other considerations which one of the following alkali
metal chlorides is expected to have the highest melting point :
Chemistrybasics-of-organic-chemistry2005easy
The reaction
is fastest when X is
Chemistrybasics-of-organic-chemistry2005easy
Due to the presence of an unpaired electron, free radicals are:
Chemistrybasics-of-organic-chemistry2005medium
The decreasing order of nucleophilicity among the nucleophiles
Chemistrythermodynamics2005easy
Consider an endothermic reaction, X → Y with the activation energies Eb and Ef
for the backward and forward reactions, respectively. In general :
Chemistrythermodynamics2005easy
Consider the reaction: N2 + 3H2 → 2NH3 carried out at constant temperature and
pressure. If ΔH and ΔU are the enthalpy and internal energy changes for the
reaction, which of the following expressions is true?
Chemistrythermodynamics2005medium
If the bond dissociation energies of XY, X2 and Y2 (all diatomic molecules) are in the ratio of 1:1:0.5 and ΔHf for the formation of XY is -200 kJ mole-1. The bond
dissociation energy of X2 will be :
Reaction of cyclohexanone with dimethylamine in the presence of catalytic amount of
an acid forms a compound if water during the reaction is continuously removed. The
compound formed is generally known as
p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to form, the compound B. The latter on acidic hydrolysis gives chiral carboxylic acid. The structure of the carboxylic acid is :
Among the following acids which has the lowest pKa value?
Chemistrysome-basic-concepts-of-chemistry2005easy
Two solutions of a substance (non electrolyte) are mixed in the following manner. 480 ml of 1.5 M first solution + 520 ml of 1.2 M second solution. What is the molarity of the final mixture?
If we consider that 1/6, in place of 1/12, mass of carbon atom is taken to be the relative atomic mass unit, the mass of one mole of the substance will
Chemistryisolation-of-elements2005easy
During the process of electrolytic refining of copper, some metals present as impurity
settle as ‘anode mud’ These are
Chemistrysolutions2005easy
If α is the degree of dissociation of Na2SO4, the vant Hoff’s factor (i) used for
calculating the molecular mass is :
Chemistrysolutions2005easy
Equimolar solutions in the same solvent have
Chemistrysolutions2005easy
Benzene and toluene form nearly ideal solutions. At 20 oC, the vapour pressure of
benzene is 75 torr and that of toluene is 22 torr. The partial vapour pressure of
benzene at 20 oC for a solution containing 78 g of benzene and 46 g of toluene in
torr is
Chemistrychemical-equilibrium2005easy
The exothermic formation of ClF3 is represented by the equation:
Cl2 (g) + 3F2 (g) ⇋ 2ClF3 (g); ΔH = -329 kJ
Which of the following will increase the quantity of ClF3 in an equilibrium mixture of
Cl2, F2 and ClF3?
Chemistrychemical-equilibrium2005easy
For the reaction
2NO2 (g) ⇋ 2NO (g) + O2 (g), (Kc = 1.8 × 10-6 at 184oC) (R = 0.0831 kJ/(mol. K))
When Kp and Kc are compared at 184oC , it is found that :