At 320 K, a gas A2 is 20% dissociated to A(g). The standard free energy change at 320 K and 1 atm in J mol-1 is approximately : (R = 8.314 JK-1 mol-1; ln2 = 0.693; ln 3 = 1.098)
Chemistrythermodynamics2018medium
Given
(i) 2Fe2O3(s) → 4Fe(s) + 3O2(g);
ΔrGo = + 1487.0 kJ mol-1
(ii) 2CO(g) + O2(g) → 2CO2(g);
ΔrGo = − 514.4 kJ mol-1
Free energy change, ΔrGo for the reaction
2Fe2O3(s) + 6CO(g) → 4Fe(s) + 6CO2(g) will be :
Chemistrythermodynamics2018medium
ΔfGo at 500 K for substance 'S' in liquid state and gaseous state are +100.7 kcl mol-1 and +103 kcal mol-1, respectively. Vapour pressure of liquid 'S' at 500 K is approximately equal to : ( R = 2 cal K-1 mol-1 )
Chemistrythermodynamics2018medium
An ideal gas undergoes a cyclic process as shown in Figure.
ΔUBC = −5 kJ mol-1, qAB = 2 kJ mol-1, WAB = −5 kJ mol-1, WCA = 3 kJ mol-1. Heat absorbed by the system during process CA is :
Chemistrythermodynamics2018easy
For which of the following reactions, ΔH is equal to ΔU?
Chemistrythermodynamics2018medium
Which of the following lines correctly show the temperature dependence of equilibrium constant K, for an
exothermic reaction?
Chemistrythermodynamics2018easy
For which of the following processes, ΔS is negative ?
Chemistrythermodynamics2018medium
The combustion of benzene(l) gives CO2(g) and H2O(l). Given that heat of combustion of benzene at constant volume is –3263.9 kJ mol–1 at 25oC; heat of combustion (in kJ mol–1) of benzene at constant pressure will be :
(R = 8.314 JK–1 mol–1)
A sample of NaClO3 is converted by heat to NaCl with a loss of 0.16g of oxygen. The residue is dissolved in water and precipitated as AgCl. The mass of AgCl (in g) obtained will be : (Given : Molar mass of AgCl=143.5gmol−1)
For per gram of reactant, the maximum quantity of N2 gas is produced in which of the following thermal decomposition reactions ?
(Given : Atomic wt. - Cr = 52 u, Ba = 137 u)
Chemistrysome-basic-concepts-of-chemistry2018easy
An unknown chlorohydrocarbon has 3.55% of chlorine. If each molecule of the hydrocarbon has one chlorine atom only; chlorine atoms present in 1 g of chlorohydrocarbon are :
(Atomic wt. of Cl = 35.5 u; Avogadro constant = 6.023 × 1023 mol-1)
The ratio of mass percent of C and H of an organic compound (CXHYOZ) is 6 : 1. If one molecule of the above compound (CXHYOZ) contains half as much oxygen as required to burn one molecule of compound CXHY completely to CO2 and H2O. The empirical formula of compound CXHYOZ is