An aromatic compound 'A' having molecular formula C7H6O2 on treating with aqueous ammonia and heating forms compound 'B'. The compound 'B' on reaction with molecular bromine and potassium hydroxide provides compound 'C' having molecular formula C6H7N.. The structure of 'A' is
Chemistrycompounds-containing-nitrogen2019medium
The major product obtained in the following reaction is :
Chemistrycompounds-containing-nitrogen2019medium
The major product formed in the reaction given below will be :
Chemistrycompounds-containing-nitrogen2019easy
The major product of following reaction is :
Chemistrycompounds-containing-nitrogen2019medium
Arrange the following amines in the decreasing order of basicity :
Chemistryelectrochemistry2019easy
Given
CO3+ + e– → CO2+ ; Eo = + 1.81 V
Pb4+
+ 2e– → Pb2+ ; Eo = + 1.67 V
Ce4+
+ e– → Ce3+
; Eo = + 1.61 V
Bi3+ + 3e– → Bi ; Eo = + 0.20 V
Oxidizing power of the species will increase in the order :
Chemistryelectrochemistry2019medium
Which one of the following graphs between molar conductivity (Λm) versus C is correct ?
Chemistryelectrochemistry2019easy
Consider the statements S1 and S2
S1 : Conductivity always increases with decrease in the concentration of electrolyte.
S2 : Molar conductivity always increases with decrease in the concentration of electrolyte.
The correct option among the following is :
Chemistryelectrochemistry2019easy
A solution of Ni(NO3)2 is electrolysed between
platinum electrodes using 0.1 Faraday
electricity. How many mole of Ni will be
deposited at the cathode?
Chemistryelectrochemistry2019easy
The standard Gibbs energy for the given cell
reaction in kJ mol–1 at 298 K is :
Zn(s) + Cu2+ (aq) → Zn2+ (aq) + Cu (s),
E° = 2 V at 298 K
(Faraday's constant, F = 96000 C mol–1)
Chemistryelectrochemistry2019medium
Calculate the standard cell potential in (V) of the
cell in which following reaction takes place :
Fe2+(aq) + Ag+(aq) → Fe3+(aq) + Ag (s)
Given that
EAg+/Ago=xVEFe2+/Feo=yVEFe3+/Feo=zV
Chemistryelectrochemistry2019medium
∧m∘ for NaCl, HCl and NaA are 126.4, 425.9 and 100.5 S cm2 mol–1, respectively. If the conductivity of 0.001 M HA is-
5 × 10–5 S cm–1, degree of dissociation of HA is -
Chemistryelectrochemistry2019medium
The standard electrode potential Eo and its temperature coefficient \left( {{{d{E^o }} \over {dT}}} \right) for a cell are 2V and − 5 × 10−4 VK−1 at 300 K respectively.
The cell reaction is
Zn(s) + Cu2+ (aq) \buildrel \, \over
\longrightarrow Zn2+ (aq) + Cu(s)
The standard reaction enthalpy (ΔrHo) at 300 K in kJ mol–1 is, [Use R = 8 JK–1 mol–1 and F = 96,000C mol–1]
Chemistryelectrochemistry2019easy
The anodic half-cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The amount of PbSO4 electrolyzed in g during the process is : (Molar mass of PbSO4 = 303 g mol−1)
Chemistryelectrochemistry2019easy
Given that EΘO2/H2O=1.23V ;
EΘS2O82−/SO42−=2.05VEΘBr2/Br−=1.09VEΘAu3+/Au=1.4V
The strongest oxidizing agent is :
Chemistryelectrochemistry2019easy
If the standard electrode potential for a cell is 2 V at 300 K, the equilibrium constant (K) for the reaction
Zn(s) + Cu2+ (aq) ⇌ Zn2+(aq) + Cu(s)
at 300 K is approximately,
(R = 8 JK−1mol−1, F = 96000 C mol−1)
Chemistryelectrochemistry2019easy
Consider the following reduction processes :
Zn2+ + 2e– → Zn(s) ; Eo = – 0.76 V
Ca2+ + 2e– → Ca(s); Eo = –2.87 V
Mg2+ + 2e– → Mg(s) ; Eo = – 2.36 V
Ni2 + 2e– → Ni(s) ; Eo = – 0.25
The reducing power of the metals increases in the order :
Chemistryelectrochemistry2019hard
For the cell Zn(s) |Zn2+ (aq)| |Mx+ (aq)| M(s), different half cells and their standard electrode potentials are given below :
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Mx+ (aq)/M(s)
Au3+(aq)/Au(s)
Ag+(aq)/Ag(s)
Fe3+(aq)/Fe2+ (aq)
Fe2+(aq)/Fe(s)
E0Mx+/M/(V)
1.40
0.80
0.77
−0.44
If Ezn2+/zn0 = − 0.76 V, which cathode will give maximum value of Eocell per electron transferred?