The correct order for acid strength of compounds :
CH ≡ CH, CH3–C ≡ CH and CH2 = CH2 is as follows
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Which compound (s) out of the following is/are not aromatic ?
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The major product of the following reaction is :
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The major product of the following reaction is
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Polysubstitution is a major drawback in:
Chemistrycoordination-compounds2019medium
The correct order of the spin-only magnetic moment of metal ions in the following low-spin
complexes, [V(CN)6]4–,[Fe(CN)6]4–, [Ru(NH3)6]3+, and [Cr(NH3)6]2+ , is :
Chemistrycoordination-compounds2019medium
The calculated spin-only magnetic moments
(BM) of the anionic and cationic species of
[Fe(H2O)6]2 and [Fe(CN)6], respectively, are :
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The degenerate orbitals of [Cr(H2O)6]3+ are :
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The one that will show optical activity is :
(en = ethane-1,2-diamine)
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The maximum possible denticities of a ligand
given below towards a common transition and
inner-transition metal ion, respectively, are :
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The correct statements among I to III are :
(I) Valence bond theory cannot explain the
color exhibited by transition metal
complexes.
(II) Valence bond theory can predict
quantitatively the magnetic properties of
transtition metal complexes.
(III) Valence bond theory cannot distinguish
ligands as weak and strong field ones.
Chemistrycoordination-compounds2019medium
The species that can have a trans-isomer is :
(en = ehane-1, 2-diamine, ox = oxalate)
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Three complexes,
[CoCl(NH3)5]
2+(I),
[Co(NH3)5H2O]3+ (II) and
[Co(NH3)6]
3+(III)
absorb light in the visible region. The correct order of the wavelength of light absorbed by them is :
Chemistrycoordination-compounds2019medium
The crystal field stabilization energy (CFSE) of [Fe(H2O)6]Cl2 and K2[NiCl4] respectively, are :
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The complex ion that will lose its crystal field stabilization energy upon oxidation of its metal to +3 state is :
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Complete removal of both the axial ligands (along the z-axis) from an octahedral complex leads to which of
the following splitting patterns? (relative orbital energies not on scale).
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The coordination numbers of Co and Al in [Co(Cl)(en)2]Cl and K3[Al(C2O4)3], respectively, are :
(en = ethane-1, 2-diamine)
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The compound used in the treatment of lead poisoning is :
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The compound that inhibits the growth of
tumors is :
Chemistrycoordination-compounds2019medium
The difference in the number of unpaired electrons of a metal ion in its high spin and low-spin octahedral complexes is two. The metal ion is :